What mass (in grams) of aspirin (C₉H₈O₄) is produced from 57.6 g of C₇H₆O₃ assuming 95.0% yield from the reaction below? C₇H₆O₃ (s) + C₄H₆O₃ (s) → C₉H₈O₄ (s) + HC₂H₃O₂ (aq).

Respuesta :

Cyu437

Answer:

71.3 g

Explanation:

molar mass of C₇H₆O₃ = 138.13 g

molar mass of [tex]C_{9}H_{8}O_{4}[/tex] = 180.17 g

find the moles of reactant: C₇H₆O₃

C₇H₆O₃ that reacted = mass/molar mass = 57.6 g C₇H₆O₃ / 138.13 g C₇H₆O₃

= 0.417 mol [tex]C_{7}H_{6}O_{3}[/tex]

From the reaction equation, 1 mole of C₇H₆O₃ yields one mole of aspirin

find theoretical yield of aspirin:

0.417 mol C7H6O3 x 180.17 g C9H8O4 / 1 mol C9H8O4[tex]\frac{0.417 mol C_{7}H_{6}O_{3}}{} x \frac{180.17 g C_{9}H_{8}O_{4}}{1 mol C_{9}H_{8}O_{4}}[/tex]

= 75.1 g C9H8O4

Actual yield= % yield × theoretical yield/100

Actual yield = 95.0 × 75.1/100

Actual yield = 71.3 g

Taking into account the reaction stoichiometry and actual yield, the mass of C₉H₈O₄ produced from 57.6 g of C₇H₆O₃ assuming 95.0% yield is 57.0285 grams.

The balanced reaction is:

22 C₇H₆O₃ (s) + 32 C₄H₆O₃ (s) → 24 C₉H₈O₄ (s) + 33 HC₂H₃O₂ (aq)

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • C₇H₆O₃: 22 moles
  • C₄H₆O₃: 32 moles
  • C₉H₈O₄: 24 moles
  • HC₂H₃O₂: 33 moles

The mass molar of each compound is:

  • C₇H₆O₃: 138 g/mole
  • C₄H₆O₃: 102 g/mole
  • C₉H₈O₄: 180 g/mole
  • HC₂H₃O₂: 60 g/mole

Then by reaction stoichiometry, the following amounts of mass of each compound participate in the reaction:

  • C₇H₆O₃: 22 moles× 138 g/mole= 3036 grams
  • C₄H₆O₃: 32 moles× 102 g/mole= 3264 grams
  • C₉H₈O₄: 24 moles× 180 g/mole= 4320 grams
  • HC₂H₃O₂: 33 moles× 60 g/mole= 1980 grams

Then you can apply the following rule of three: if by stoichiometry 3036 grams of C₇H₆O₃ produce 3264 grams of C₉H₈O₄, 57.6 grams of C₇H₆O₃ will produce how many mass of C₉H₈O₄?

[tex]mass of C_{9} H_{8} O_{4} =\frac{57.6 grams of C_{7} H_{6} O_{3} x3264 gramsof C_{9} H_{8} O_{4} }{3036 grams of C_{7} H_{6} O_{3}}[/tex]

mass of C₉H₈O₄= 60.03 grams

On the other side, actual yield is the amount of product actually obtained from a reaction. Assuming 95.0% yield  and considering the previously calculated mass the maximum amount of product that can be produced in the reaction, you can apply the following rule of three:  If 100% equals 60.03 grams of the compound produced, 95% equals how much mass of the compound?

[tex]mass of C_{9} H_{8} O_{4} =\frac{95 percentx60.03gramsof C_{9} H_{8} O_{4} }{100 percent}[/tex]

mass of C₉H₈O₄= 57.0285 grams

Finally, the mass of C₉H₈O₄ produced from 57.6 g of C₇H₆O₃ assuming 95.0% yield is 57.0285 grams.

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