Enter your answer in the provided box. High levels of ozone (O3) make rubber deteriorate, green plants turn brown, and cause people to have difficulty breathing. Calculate ΔG at 298 K for the formation of 1 mole of O3 from O2 in urban smog, where [O2] = 0.210 atm and [O3] = 5.00 × 10−7 atm.

Respuesta :

Answer:

[tex]\Delta G=133053.681574\ J[/tex]

Explanation:

T = Temperature = 298 K

[tex]n_{O_3}=1\ mole[/tex]

[tex][O_2]=0.21\ atm[/tex]

[tex][O_3]=5\times 10^{-7}\ atm[/tex]

Reaction quotient is given by

[tex]Q=\dfrac{P(O_3)}{P(O_2)^{1.5}}\\\Rightarrow Q=\dfrac{5\times 10^{-7}}{(0.21)^{1.5}}\\\Rightarrow Q=0.00000519566405324[/tex]

[tex]\Delta G^{\circ}=1\times\Delta G_f^{\circ}O_3-1.5\Delta G_f^{\circ}O_2\\\Rightarrow \Delta G^{\circ}=1\times 163.2-1.5\times 0\\\Rightarrow \Delta G^{\circ}=163.2\ kJ[/tex]

We know that

[tex]\Delta G=\Delta G^{\circ}+RTlnQ\\\Rightarrow \Delta G=163200+(8.314\times 298)\times ln(0.00000519566405324)\\\Rightarrow \Delta G=133053.681574\ J[/tex]

[tex]\Delta G=133053.681574\ J[/tex]