At a certain temperature, this reaction establishes an equilibrium with the given equilibrium constant, Kc. 3 A ( g ) + 2 B ( g ) − ⇀ ↽ − 4 C ( g ) K c = 2.93 × 10 29 If, at this temperature, 2.30 mol of A and 3.90 mol of B are placed in a 1.00 L container, what are the concentrations of A, B, and C at equilibrium?

Respuesta :

Answer: The equilibrium concentration of A, B and C are 0.02 M, 2.38 M and 3.04 M respectively.

Explanation:

We are given:

Initial moles of A = 2.30 moles

Initial moles of B = 3.90 moles

Volume of the container = 1.00 L

Concentration of a substance is calculated by:

[tex]\text{Concentration}=\frac{\text{Number of moles}}{\text{Volume}}[/tex]

So, concentration of A = [tex]\frac{2.30}{1.00}=2.30M[/tex]

Concentration of B = [tex]\frac{3.90}{1.00}=3.90M[/tex]

The given chemical equation follows:

                     [tex]3A(g)+2B(g)\rightleftharpoons 4C(g)[/tex]

Initial:          2.30       3.90

At eqllm:   2.30-3x   3.90-2x    4x

The expression of [tex]K_c[/tex] for above equation follows:

[tex]K_c=\frac{[C]^4}{[A]^3\times [B]^2}[/tex]

We are given:

[tex]K_c=2.93\times 10^{29}[/tex]

Putting values in above expression, we get:

[tex]2.93\times 10^{29}=\frac{(4x)^4}{(2.30-3x)^3\times (3.90\times 2x)^2}\\\\x=0.76[/tex]

So, the equilibrium concentration of A = [tex](2.30-3x)=(2.30-(3\times 0.76))=0.02M[/tex]

The equilibrium concentration of B = [tex](3.90-2x)=(3.90-(2\times 0.76))=2.38M[/tex]

The equilibrium concentration of C = [tex]4x=(4\times 0.76)=3.04M[/tex]

Hence, the equilibrium concentration of A, B and C are 0.02 M, 2.38 M and 3.04 M respectively.

The equilibrium is the condition of constant rate of reaction. The equilibrium concentration of A is 0.02 M, B is 2.38, and C is 3.04 M.

What is equilibrium constant?

The equilibrium constant is the ratio of the concentration of product and reactant at equilibrium.

The initial concentration of A and B in 1 L of the solution is given as:

[tex]\rm Molarity=\dfrac{Moles}{Volume}[/tex]

The volume is 1L, thus molarity is equal to moles.

So, the concentration of A is 2.30 M, and the concentration of B is 3.90 M.

The equilibrium concentration of A, B, and C is given in the image attached.

The equilibrium constant ([tex]K_c[/tex]) for the reaction is given as:

[tex]K_c=\rm \dfrac{[C]^4}{[A]^3[B]^2}[/tex]

Substituting the value of A, B, C and equilibrium constant:

[tex]2.93\;\times\;10^{29}=\dfrac{(4x)^4}{(2.30-3x)^3\;\times\;(3.90-2x)^2}\\ x=0.76[/tex]

The equilibrium concentration for the reaction is given as:

  • [tex]\text A=2.30-3x\\\text A=2.30-3(0.76)\\\text A=0.02\;\text M[/tex]

The concentration of A at equilibrium is 0.02M.

  • [tex]\text B=3.90-2x\\\text B=3.90-2(0.76)\\\text B=2.38\;\rm M[/tex]

The concentration of B at equilibrium is 2.38 M.

  • [tex]\text C=4x\\\text C=4(0.76)\\\rm C=3.04\;M[/tex]

The concentration of C at equilibrium is 3.04 M.

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